Photocatalytic Degradation of Pharmaceutical Waste Using ZnO/CuO Thin Films Under Visible Light

Dara Vann (1), Ravi Dara (2), Thiago Rocha (3), Siti Shofiah (4)
(1) Royal University Agriculture, Cambodia,
(2) South East University, Cambodia,
(3) Universidade Federal Bahia, Brazil,
(4) Politeknik Keselamatan Transportasi Jalan, Indonesia

Abstract

The increasing presence of persistent pharmaceutical contaminants in water bodies poses a significant threat to environmental and human health, necessitating effective remediation technologies. This study aimed to develop and evaluate zinc oxide/copper oxide (ZnO/CuO) composite thin films as an efficient photocatalyst for degrading pharmaceutical waste under visible light. The ZnO/CuO thin films were synthesized via a sol-gel spin-coating method, and their photocatalytic activity was assessed using diclofenac as a model pollutant. The results demonstrated that the ZnO/CuO heterostructure exhibited enhanced visible light absorption and superior photocatalytic performance compared to pure ZnO. The composite films achieved over 90% degradation of diclofenac within 120 minutes, with the process following pseudo-first-order kinetics. The enhanced efficiency is attributed to effective charge separation at the ZnO/CuO interface. This research confirms that ZnO/CuO thin films are promising, reusable photocatalysts for the sustainable treatment of pharmaceutical-contaminated water.

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References

Arianto, T., Adrias, A., Septriani, S., & Yulika, F. (2024). The ethnoecology of the Malay sacred myth through narratives of Kampung Tua Nongsa in Batam. Studies in English Language and Education, 11(1), 568–586. https://doi.org/10.24815/siele.v11i1.19006

Bahuchet, S., & Bognon, M. (2023). Trends for Ethnoecology in the French-Speaking Tropics and Beyond: Origins and Evolution. Dalam K. Ikeya & W. Balée (Ed.), Global Ecology in Historical Perspective (hlm. 21–49). Springer Nature Singapore. https://doi.org/10.1007/978-981-19-6557-9_2

Bogotá-Gregory, J. D., Jaramillo Hurtado, L. F., Guhl Samudio, J. F., & Agudelo Córdoba, E. (2024). Ethnoecology and use of fishes by the Cubeo people from the Cuduyarí River, Colombian Amazonia. Journal of Ethnobiology and Ethnomedicine, 20(1), 101. https://doi.org/10.1186/s13002-024-00737-1

Brzi?, I., Brener, M., ?arni, A., ?ušterevska, R., ?ulig, B., Dziuba, T., Golub, V., Irimia, I., Jelakovi?, B., Kavgac?, A., Krstivojevi? ?uk, M., Krstonoši?, D., Stupar, V., Trobonja?a, Z., & Škvorc, Ž. (2023). Different Ecological Niches of Poisonous Aristolochia clematitis in Central and Marginal Distribution Ranges—Another Contribution to a Better Understanding of Balkan Endemic Nephropathy. Plants, 12(17), 3022. https://doi.org/10.3390/plants12173022

Chakocha, A. F. N., Avana, M.-L. T., Momo, M. C. S., Rimlinger, A., Mboujda, F. M. M., & Duminil, J. (2025). Ethnoecological Knowledge and Management Strategies for Canarium schweinfurthii (Burseraceae) in Forest and Savanna Zones of Cameroon. Economic Botany. https://doi.org/10.1007/s12231-025-09633-5

Department of Science Education, Universitas Negeri Semarang, Central Java, Indonesia, Rohman, M. H., Marwoto, P., Department of Science Education, Universitas Negeri Semarang, Central Java, Indonesia, Nugroho, S. E., Department of Science Education, Universitas Negeri Semarang, Central Java, Indonesia, Supriyadi, S., & Department of Science Education, Universitas Negeri Semarang, Central Java, Indonesia. (2024). Effectiveness of Ethnoecological-STEM Project-Based Learning Model to Improve Critical Thinking Skills, Creativity, and Science Concept Mastery. International Journal of Cognitive Research in Science, Engineering and Education, 12(3), 521–534. https://doi.org/10.23947/2334-8496-2024-12-3-521-534

Dragomeretskaya, A., Bebenina, L., Trotsenko, O., & Gaer, S. (2022). Traditional Lifestyle of the Indigenous Population of the Khabarovsk Kraias a Factor Determining the Spread of Helminth Infections. ???????? ????????? ? ????? ???????? - ????? / PUBLIC HEALTH AND LIFE ENVIRONMENT, 72–77. https://doi.org/10.35627/2219-5238/2022-30-3-72-77

Fatmawati, N. & Sanusi. (2024). Ethnoecology: The Community Adaptation Patterns of Forest Management in Grobogan Central Java. Jurnal Penelitian Kehutanan Wallacea, 13(2), 55–65. https://doi.org/10.24259/jpkwallacea.v13i2.32146

Forero, O. A., Rúa Bustamante, C., & Zambrano Ortiz, J. R. (2023). Beyond Animal Husbandry: The Role of Herders Among the Wayuu of Colombia. Human Ecology, 51(4), 627–640. https://doi.org/10.1007/s10745-023-00416-x

Griffiths, B. M., Gonzales, T., & Gilmore, M. P. (2023). Spatiotemporal variation in hunting in a riverine indigenous community in the Amazon. Biodiversity and Conservation, 32(3), 1005–1018. https://doi.org/10.1007/s10531-022-02535-1

Klokov, K. (2023). Indigenous hunting in the Russian Arctic: Toward sustainable wildlife resource management. E3S Web of Conferences, 378, 05004. https://doi.org/10.1051/e3sconf/202337805004

Kuklina, V. V., Bocharnikov, V. N., Davydov, V. N., Kambalin, V. S., Vashukevich, E. V., & Vashukevich, Y. E. (2022). Hunting in Siberia: Between Subsistence Practices and Natural Resource Management. Dalam V. N. Bocharnikov & A. N. Steblyanskaya (Ed.), Humans in the Siberian Landscapes (hlm. 333–355). Springer International Publishing. https://doi.org/10.1007/978-3-030-90061-8_15

Kurz, D. J., Connor, T., Brodie, J. F., Baking, E. L., Szeto, S. H., Hearn, A. J., Gardner, P. C., Wearn, O. R., Deith, M. C. M., Deere, N. J., Ampeng, A., Bernard, H., Goon, J., Granados, A., Helmy, O., Lim, H.-Y., Luskin, M. S., Macdonald, D. W., Ross, J., … Brashares, J. S. (2023). Socio-ecological factors shape the distribution of a cultural keystone species in Malaysian Borneo. Npj Biodiversity, 2(1), 4. https://doi.org/10.1038/s44185-022-00008-w

Leete, A. (2022). Finno-Ugric Indigenous Knowledge, Hybridity and Co-Creation in Research: The Komi Case. Journal of Ethnology and Folkloristics, 16(2), 86–103. https://doi.org/10.2478/jef-2022-0014

Lidberg, W., Westphal, F., Brax, C., Sandström, C., & Östlund, L. (2024). Detection of Hunting Pits using Airborne Laser Scanning and Deep Learning. Journal of Field Archaeology, 49(6), 395–405. https://doi.org/10.1080/00934690.2024.2364428

Marquez, V., Carbone, L. M., Jiménez-Escobar, N. D., Britos, A. H., Aguilar, R., & Zamudio, F. (2024). Local ecological knowledge of forage plants for goat farming and perceptions about pollination of tree species in the arid Chaco. Journal of Arid Environments, 222, 105167. https://doi.org/10.1016/j.jaridenv.2024.105167

Pontón-Cevallos, J., Ramírez-Valarezo, N., Pozo-Cajas, M., Rodríguez-Jácome, G., Navarrete-Forero, G., Moity, N., Villa-Cox, G., Ramírez-González, J., Barragán-Paladines, M. J., Bermúdez-Monsalve, J. R., & Goethals, P. L. M. (2022). Fishers’ Local Ecological Knowledge to Support Mangrove Research in the Galapagos. Frontiers in Marine Science, 9, 911109. https://doi.org/10.3389/fmars.2022.911109

Rai, S. C., & Mishra, P. K. (2022). Traditional Ecological Knowledge and Resource Management: A Conceptual Framework. Dalam S. C. Rai & P. K. Mishra (Ed.), Traditional Ecological Knowledge of Resource Management in Asia (hlm. 1–11). Springer International Publishing. https://doi.org/10.1007/978-3-031-16840-6_1

Russell, S. R., Sultana, R., Rangers, N. Y., & Ens, E. J. (2023). Mepimbat tedul proujek: Indigenous knowledge of culturally significant freshwater turtles addresses species knowledge gaps in Northern Australia. Austral Ecology, 48(7), 1306–1327. https://doi.org/10.1111/aec.13353

Santi, T., & Prado, H. M. (2022). Etnoecologia e o campesinato no sudoeste paulista: Práticas tradicionais e saber ambiental em perspectiva. Desenvolvimento e Meio Ambiente, 59. https://doi.org/10.5380/dma.v59i0.77173

Schiøtt, S., Tejsner, P., & Rysgaard, S. (2022). Inuit and Local Knowledge on the Marine Ecosystem in Ilulissat Icefjord, Greenland. Human Ecology, 50(1), 167–181. https://doi.org/10.1007/s10745-021-00277-2

Slade, E., McKechnie, I., & Salomon, A. K. (2022). Archaeological and Contemporary Evidence Indicates Low Sea Otter Prevalence on the Pacific Northwest Coast During the Late Holocene. Ecosystems, 25(3), 548–566. https://doi.org/10.1007/s10021-021-00671-3

Stevens, M., Paul, K. L., Lunstrum, E., Edmo, T., & Maxwell, B. (2025). Rethinking Indigenous Hunting in National Parks. Annals of the American Association of Geographers, 1–14. https://doi.org/10.1080/24694452.2024.2440412

Sucholas, J., Molnár, Z., ?uczaj, ?., & Poschlod, P. (2022). Local traditional ecological knowledge about hay management practices in wetlands of the Biebrza Valley, Poland. Journal of Ethnobiology and Ethnomedicine, 18(1), 9. https://doi.org/10.1186/s13002-022-00509-9

Sullivan, S. (2023). “Hunting Africa”: How international trophy hunting may constitute neocolonial green extractivism. Journal of Political Ecology, 30(1). https://doi.org/10.2458/jpe.5489

Tagliari, M. M., Bogoni, J. A., Blanco, G. D., Cruz, A. P., & Peroni, N. (2023). Disrupting a socio-ecological system: Could traditional ecological knowledge be the key to preserving the Araucaria Forest in Brazil under climate change? Climatic Change, 176(2), 2. https://doi.org/10.1007/s10584-022-03477-x

Tefera Dibaba, A., & Barkessa, A. (2025). 2. Ecopoetic and Ecolinguistic Approaches to ‘Broken Places’: Orature of Displacement Around the Ethiopian Capital. Dalam S. Marzagora & F. Orsini (Ed.), World Oral Literature Series (1 ed., Vol. 12, hlm. 83–112). Open Book Publishers. https://doi.org/10.11647/obp.0405.02

Authors

Dara Vann
daravannn@gmail.com (Primary Contact)
Ravi Dara
Thiago Rocha
Siti Shofiah
Vann, D., Dara, R., Rocha, T., & Shofiah, S. (2025). Photocatalytic Degradation of Pharmaceutical Waste Using ZnO/CuO Thin Films Under Visible Light. Research of Scientia Naturalis, 2(3), 148–161. https://doi.org/10.70177/scientia.v2i3.2384

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