Electrochemical Techniques in Energy Storage: Advances in Supercapacitors

Catherine Lie (1), Samantha Gonzales (2), Dina Ahmed (3)
(1) University of Mindanao, Philippines,
(2) University of Santo Tomas, Philippines,
(3) Mansoura University, Egypt

Abstract

has driven significant advancements in electrochemical techniques, particularly in the development of supercapacitors. These devices offer rapid charge and discharge capabilities, making them suitable for various applications, including renewable energy systems and electric vehicles. This study aims to explore the recent advancements in supercapacitor technology through the application of novel electrochemical techniques. The focus is on improving energy density, power density, and cycle life to enhance the overall performance of supercapacitors. A comprehensive review of recent literature was conducted, highlighting innovative materials and techniques used in supercapacitor design. Experimental work involved synthesizing new electrode materials and characterizing their electrochemical performance using techniques such as cyclic voltammetry and electrochemical impedance spectroscopy. Findings indicate that the integration of advanced materials, such as graphene and metal-organic frameworks (MOFs), significantly enhances the electrochemical performance of supercapacitors. The study demonstrated improvements in energy density by up to 50% and power density by 30%, along with extended cycle life under various operational conditions.

Full text article

Generated from XML file

References

Akhade, S. A., Singh, N., Gutiérrez, O. Y., Lopez-Ruiz, J., Wang, H., Holladay, J. D., Liu, Y., Karkamkar, A., Weber, R. S., Padmaperuma, A. B., Lee, M.-S., Whyatt, G. A., Elliott, M., Holladay, J. E., Male, J. L., Lercher, J. A., Rousseau, R., & Glezakou, V.-A. (2020). Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review. Chemical Reviews, 120(20), 11370–11419. https://doi.org/10.1021/acs.chemrev.0c00158

Ali, Md. A., Hu, C., Jahan, S., Yuan, B., Saleh, M. S., Ju, E., Gao, S., & Panat, R. (2021). Sensing of COVID?19 Antibodies in Seconds via Aerosol Jet Nanoprinted Reduced?Graphene?Oxide?Coated 3D Electrodes. Advanced Materials, 33(7), 2006647. https://doi.org/10.1002/adma.202006647

Chaibun, T., Puenpa, J., Ngamdee, T., Boonapatcharoen, N., Athamanolap, P., O’Mullane, A. P., Vongpunsawad, S., Poovorawan, Y., Lee, S. Y., & Lertanantawong, B. (2021). Rapid electrochemical detection of coronavirus SARS-CoV-2. Nature Communications, 12(1), 802. https://doi.org/10.1038/s41467-021-21121-7

Chang, C.-J., Lin, S.-C., Chen, H.-C., Wang, J., Zheng, K. J., Zhu, Y., & Chen, H. M. (2020). Dynamic Reoxidation/Reduction-Driven Atomic Interdiffusion for Highly Selective CO2 Reduction toward Methane. Journal of the American Chemical Society, 142(28), 12119–12132. https://doi.org/10.1021/jacs.0c01859

Chao, D., Ye, C., Xie, F., Zhou, W., Zhang, Q., Gu, Q., Davey, K., Gu, L., & Qiao, S. (2020). Atomic Engineering Catalyzed MnO2 Electrolysis Kinetics for a Hybrid Aqueous Battery with High Power and Energy Density. Advanced Materials, 32(25), 2001894. https://doi.org/10.1002/adma.202001894

Cui, F., & Zhou, H. S. (2020). Diagnostic methods and potential portable biosensors for coronavirus disease 2019. Biosensors and Bioelectronics, 165, 112349. https://doi.org/10.1016/j.bios.2020.112349

Fabiani, L., Saroglia, M., Galatà, G., De Santis, R., Fillo, S., Luca, V., Faggioni, G., D’Amore, N., Regalbuto, E., Salvatori, P., Terova, G., Moscone, D., Lista, F., & Arduini, F. (2021). Magnetic beads combined with carbon black-based screen-printed electrodes for COVID-19: A reliable and miniaturized electrochemical immunosensor for SARS-CoV-2 detection in saliva. Biosensors and Bioelectronics, 171, 112686. https://doi.org/10.1016/j.bios.2020.112686

Fan, K., Xie, W., Li, J., Sun, Y., Xu, P., Tang, Y., Li, Z., & Shao, M. (2022). Active hydrogen boosts electrochemical nitrate reduction to ammonia. Nature Communications, 13(1), 7958. https://doi.org/10.1038/s41467-022-35664-w

Guo, L., Tan, J., Kaya, S., Leng, S., Li, Q., & Zhang, F. (2020). Multidimensional insights into the corrosion inhibition of 3,3-dithiodipropionic acid on Q235 steel in H2SO4 medium: A combined experimental and in silico investigation. Journal of Colloid and Interface Science, 570, 116–124. https://doi.org/10.1016/j.jcis.2020.03.001

Guo, X., Gu, J., Lin, S., Zhang, S., Chen, Z., & Huang, S. (2020). Tackling the Activity and Selectivity Challenges of Electrocatalysts toward the Nitrogen Reduction Reaction via Atomically Dispersed Biatom Catalysts. Journal of the American Chemical Society, 142(12), 5709–5721. https://doi.org/10.1021/jacs.9b13349

Han, N., Ding, P., He, L., Li, Y., & Li, Y. (2020). Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate. Advanced Energy Materials, 10(11), 1902338. https://doi.org/10.1002/aenm.201902338

Han, X., Sheng, H., Yu, C., Walker, T. W., Huber, G. W., Qiu, J., & Jin, S. (2020). Electrocatalytic Oxidation of Glycerol to Formic Acid by CuCo2 O4 Spinel Oxide Nanostructure Catalysts. ACS Catalysis, 10(12), 6741–6752. https://doi.org/10.1021/acscatal.0c01498

He, H., Tong, H., Song, X., Song, X., & Liu, J. (2020). Highly stable Zn metal anodes enabled by atomic layer deposited Al2 O3 coating for aqueous zinc-ion batteries. Journal of Materials Chemistry A, 8(16), 7836–7846. https://doi.org/10.1039/D0TA00748J

Hooda, A., Goyat, M. S., Pandey, J. K., Kumar, A., & Gupta, R. (2020). A review on fundamentals, constraints and fabrication techniques of superhydrophobic coatings. Progress in Organic Coatings, 142, 105557. https://doi.org/10.1016/j.porgcoat.2020.105557

Jiang, W.-J., Tang, T., Zhang, Y., & Hu, J.-S. (2020). Synergistic Modulation of Non-Precious-Metal Electrocatalysts for Advanced Water Splitting. Accounts of Chemical Research, 53(6), 1111–1123. https://doi.org/10.1021/acs.accounts.0c00127

Jin, Z., Li, H., & Li, J. (2022). Efficient photocatalytic hydrogen evolution over graphdiyne boosted with a cobalt sulfide formed S-scheme heterojunction. Chinese Journal of Catalysis, 43(2), 303–315. https://doi.org/10.1016/S1872-2067(21)63818-4

Kamkeng, A. D. N., Wang, M., Hu, J., Du, W., & Qian, F. (2021). Transformation technologies for CO2 utilisation: Current status, challenges and future prospects. Chemical Engineering Journal, 409, 128138. https://doi.org/10.1016/j.cej.2020.128138

Kumaravel, V., Bartlett, J., & Pillai, S. C. (2020). Photoelectrochemical Conversion of Carbon Dioxide (CO2 ) into Fuels and Value-Added Products. ACS Energy Letters, 5(2), 486–519. https://doi.org/10.1021/acsenergylett.9b02585

Lee, Y.-G., Fujiki, S., Jung, C., Suzuki, N., Yashiro, N., Omoda, R., Ko, D.-S., Shiratsuchi, T., Sugimoto, T., Ryu, S., Ku, J. H., Watanabe, T., Park, Y., Aihara, Y., Im, D., & Han, I. T. (2020). High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes. Nature Energy, 5(4), 299–308. https://doi.org/10.1038/s41560-020-0575-z

Manjakkal, L., Szwagierczak, D., & Dahiya, R. (2020). Metal oxides based electrochemical pH sensors: Current progress and future perspectives. Progress in Materials Science, 109, 100635. https://doi.org/10.1016/j.pmatsci.2019.100635

Mefford, J. T., Akbashev, A. R., Kang, M., Bentley, C. L., Gent, W. E., Deng, H. D., Alsem, D. H., Yu, Y.-S., Salmon, N. J., Shapiro, D. A., Unwin, P. R., & Chueh, W. C. (2021). Correlative operando microscopy of oxygen evolution electrocatalysts. Nature, 593(7857), 67–73. https://doi.org/10.1038/s41586-021-03454-x

Mohanraj, J., Durgalakshmi, D., Rakkesh, R. A., Balakumar, S., Rajendran, S., & Karimi-Maleh, H. (2020). Facile synthesis of paper based graphene electrodes for point of care devices: A double stranded DNA (dsDNA) biosensor. Journal of Colloid and Interface Science, 566, 463–472. https://doi.org/10.1016/j.jcis.2020.01.089

Munteanu, I. G., & Apetrei, C. (2021). Analytical Methods Used in Determining Antioxidant Activity: A Review. International Journal of Molecular Sciences, 22(7), 3380. https://doi.org/10.3390/ijms22073380

Qian, Q., Zhang, J., Li, J., Li, Y., Jin, X., Zhu, Y., Liu, Y., Li, Z., El?Harairy, A., Xiao, C., Zhang, G., & Xie, Y. (2021). Artificial Heterointerfaces Achieve Delicate Reaction Kinetics towards Hydrogen Evolution and Hydrazine Oxidation Catalysis. Angewandte Chemie International Edition, 60(11), 5984–5993. https://doi.org/10.1002/anie.202014362

Raziq, A., Kidakova, A., Boroznjak, R., Reut, J., Öpik, A., & Syritski, V. (2021). Development of a portable MIP-based electrochemical sensor for detection of SARS-CoV-2 antigen. Biosensors and Bioelectronics, 178, 113029. https://doi.org/10.1016/j.bios.2021.113029

Röckl, J. L., Pollok, D., Franke, R., & Waldvogel, S. R. (2020). A Decade of Electrochemical Dehydrogenative C,C-Coupling of Aryls. Accounts of Chemical Research, 53(1), 45–61. https://doi.org/10.1021/acs.accounts.9b00511

Shang, H., Sun, W., Sui, R., Pei, J., Zheng, L., Dong, J., Jiang, Z., Zhou, D., Zhuang, Z., Chen, W., Zhang, J., Wang, D., & Li, Y. (2020). Engineering Isolated Mn–N2 C2 Atomic Interface Sites for Efficient Bifunctional Oxygen Reduction and Evolution Reaction. Nano Letters, 20(7), 5443–5450. https://doi.org/10.1021/acs.nanolett.0c01925

Siu, J. C., Fu, N., & Lin, S. (2020). Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery. Accounts of Chemical Research, 53(3), 547–560. https://doi.org/10.1021/acs.accounts.9b00529

Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022). Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis. Chemical Reviews, 122(2), 2487–2649. https://doi.org/10.1021/acs.chemrev.1c00384

Theerthagiri, J., Lee, S. J., Karuppasamy, K., Arulmani, S., Veeralakshmi, S., Ashokkumar, M., & Choi, M. Y. (2021). Application of advanced materials in sonophotocatalytic processes for the remediation of environmental pollutants. Journal of Hazardous Materials, 412, 125245. https://doi.org/10.1016/j.jhazmat.2021.125245

Yakoh, A., Pimpitak, U., Rengpipat, S., Hirankarn, N., Chailapakul, O., & Chaiyo, S. (2021). Paper-based electrochemical biosensor for diagnosing COVID-19: Detection of SARS-CoV-2 antibodies and antigen. Biosensors and Bioelectronics, 176, 112912. https://doi.org/10.1016/j.bios.2020.112912

Yang, Y., Louisia, S., Yu, S., Jin, J., Roh, I., Chen, C., Fonseca Guzman, M. V., Feijóo, J., Chen, P.-C., Wang, H., Pollock, C. J., Huang, X., Shao, Y.-T., Wang, C., Muller, D. A., Abruña, H. D., & Yang, P. (2023). Operando studies reveal active Cu nanograins for CO2 electroreduction. Nature, 614(7947), 262–269. https://doi.org/10.1038/s41586-022-05540-0

Ye, Y., Yang, D., Chen, H., Guo, S., Yang, Q., Chen, L., Zhao, H., & Wang, L. (2020). A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment. Journal of Hazardous Materials, 381, 121019. https://doi.org/10.1016/j.jhazmat.2019.121019

Zarabi Golkhatmi, S., Asghar, M. I., & Lund, P. D. (2022). A review on solid oxide fuel cell durability: Latest progress, mechanisms, and study tools. Renewable and Sustainable Energy Reviews, 161, 112339. https://doi.org/10.1016/j.rser.2022.112339

Zhang, N., Zhang, X., Tao, L., Jiang, P., Ye, C., Lin, R., Huang, Z., Li, A., Pang, D., Yan, H., Wang, Y., Xu, P., An, S., Zhang, Q., Liu, L., Du, S., Han, X., Wang, D., & Li, Y. (2021). Silver Single?Atom Catalyst for Efficient Electrochemical CO2 Reduction Synthesized from Thermal Transformation and Surface Reconstruction. Angewandte Chemie International Edition, 60(11), 6170–6176. https://doi.org/10.1002/anie.202014718

Zhou, W., Chen, M., Tian, Q., Chen, J., Xu, X., & Wong, C.-P. (2022). Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries. Energy Storage Materials, 44, 57–65. https://doi.org/10.1016/j.ensm.2021.10.002

Zinatloo-Ajabshir, S., Morassaei, M. S., Amiri, O., Salavati-Niasari, M., & Foong, L. K. (2020). Nd2Sn2O7 nanostructures: Green synthesis and characterization using date palm extract, a potential electrochemical hydrogen storage material. Ceramics International, 46(11), 17186–17196. https://doi.org/10.1016/j.ceramint.2020.03.014

Authors

Catherine Lie
cathrinelie@gmail.com (Primary Contact)
Samantha Gonzales
Dina Ahmed
Lie, C., Gonzales, S., & Ahmed, D. (2025). Electrochemical Techniques in Energy Storage: Advances in Supercapacitors. Research of Scientia Naturalis, 2(2), 92–101. https://doi.org/10.70177/scientia.v2i2.2011

Article Details

Most read articles by the same author(s)